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• W2007722433 abstract "The kinetics and mechanism of the reactions of O-ethyl S-(Z)aryl thiocarbonates with (X)benzylamines in acetonitrile at 45.0°C are studied. Relatively small values of βX(βnuc) = 0.6 ∼ 0.8 and βZ (βlg) = −0.5 ∼ −0.7 together with a negative cross-interaction constant ρXZ (= −0.47) and failure of the reactivity–selectivity principle (RSP) are interpreted to indicate a concerted mechanism. The normal kinetic isotope effects (kH/kD = 1.3 ∼ 1.8) involving deuterated benzylamine nucleophiles suggest a hydrogen-bonded, four-center-type transition state. © 2000 John Wiley & Sons, Inc. Int J Chem Kinet 32: 131–135, 2000" @default.
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• W2007722433 date "2000-01-01" @default.
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• W2007722433 title "Kinetics and mechanism of the aminolysis ofO-ethylS-aryl thiocarbonates in acetonitrile" @default.
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• W2007722433 doi "https://doi.org/10.1002/(sici)1097-4601(2000)32:3<131::aid-kin2>3.0.co;2-c" @default.
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