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- W2007724586 abstract "Abstract Carbocyclization has been selectively achieved over epoxide formation from a γ-chloro-δ-hydroxy-ketone in the presence of a lithiumamide or using a different strategy in which the related silyloxyenol ether bearing an iodine atom at gamma-position and a silyloxy group in delta-position is reacted with tetrabutylammonium fluoride. These approaches take advantage of (i) the poor reactivity of the intermediate β-halogeno lithiumalkoxide first formed in the former case and (ii) the poorer ability of the fluoride ion to desilylate a silyl ether over a silylenol ether." @default.
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- W2007724586 date "2010-04-01" @default.
- W2007724586 modified "2023-09-23" @default.
- W2007724586 title "Competing cyclopropane over epoxide formation from γ-halogeno-δ-hydroxy-ketones" @default.
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- W2007724586 doi "https://doi.org/10.1016/j.tetlet.2010.02.003" @default.
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