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- W2007755781 abstract "Abstract Mononuclear Mn(II), Co(II), and Cu(II) pivalates were synthesized for the first time. They were isolated as salts with a composition NBu4[MPiv3], where Piv is the pivalate anion. In the structure of the [MnPiv3] and [CoPiv3] coordination units, the environment of the central atom was found to be close to a trigonal prism. In [CuPiv3], the distorted square environment of Cu is formed by one bidentate O,O′-Piv and two monodentate Piv’s; the second O atoms of monodentate Piv’s tend to occupy the positions close to the apical positions of the elongated octahedron. An X-ray diffraction study of NBu4[CoPiv3] and NBu4[CuPiv3] crystals showed strong disordering of the O atoms of the coordinated carboxylate groups at room temperature, which was suppressed when NBu4[CoPiv3] was cooled to 85 K and NBu4[CuPiv3] to 30 K. In the synthesis of NBu4[CoPiv3] and NBu4[CuPiv3], new compounds, namely, tetranuclear (NBu4)2[Co4Piv8(AcO)2(H2O)4] and (NBu4)2[Cu4Piv8(AcO)2(H2O)2], respectively, formed along with the major product." @default.
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- W2007755781 date "2014-10-01" @default.
- W2007755781 modified "2023-10-14" @default.
- W2007755781 title "Mononuclear Mn(II), Co(II), and Cu(II) pivalates" @default.
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- W2007755781 doi "https://doi.org/10.1016/j.poly.2014.05.057" @default.
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