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- W2007755794 abstract "Dihydroxylation of ene ester systems was achieved in good yield and diastereoselectivity under classical catalytic OsO4 and NMO conditions using the intrinsic diastereoselectivity in α-methyl β-OTBS systems. This intrinsic diastereoselection can be reversed using ‘super’ AD-mix to give the opposite diastereomer also in good selectivity. The regioselection of dihydroxylation in diene esters using a modified ‘super’ AD-mix was poor. This methodology can be applied towards the synthesis of part structures of the marine macrolide Altohyrtin A." @default.
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- W2007755794 date "1998-10-01" @default.
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- W2007755794 title "An efficient protocol for the stereoselective dihydroxylation of ene-ester systems" @default.
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- W2007755794 doi "https://doi.org/10.1016/s0040-4020(98)00800-x" @default.
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