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- W2007759503 abstract "Sulfuric acid immobilized on silica gel (H2SO4-SiO2) was used as an efficient and convenient promoter for Ferrier-type rearrangement of 3,4,6-tri-O-benzyl-d-glucal in CH2Cl2, which is a difficult donor for this type of reaction. The acceptors include primary alcohols, secondary alcohols, pentanol, halogenated alcohol, sterols, thiol, and 2-naphthol. Thus, 2,3-unsaturated glycosides were obtained rapidly (<2 h) and efficiently (>62%) in good α-selectivity (α/β>4.2:1) under mild conditions." @default.
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- W2007759503 date "2013-07-24" @default.
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- W2007759503 title "A Facile H2SO4-SiO2–Catalyzed Ferrier Rearrangement of 3,4,6-Tri-O-benzyl-d-glucal" @default.
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- W2007759503 doi "https://doi.org/10.1080/07328303.2013.809093" @default.
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