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- W2007782021 abstract "Vibronic progressions are programmed into a pulse shaper which converts them via the inherent Fourier transformation into a train of femtosecond pulses in time domain for chromophore excitation. Double pulse results agree with phase-sensitive wave packet superposition from a Michelson interferometer which delivers coherence times with high reliability. Spectral resolution of 1 nm and a spacing of around 4 nm within the 20 nm envelope centered at 590 nm delivers a train of seven phase-controlled 40 fs subpulses separated by 250 fs. Combs adjusted to the zero phonon lines (ZPL) and phonon sidebands (PSB) of the B state vibronic progression are reproduced in the chromophore for a coherent subpulse accumulation. B state ZPL wave packet dynamics dominates in pump-probe spectra due to its coherence despite an overwhelming but incoherent A state contribution in absorption. PSB comb accumulation is also phase sensitive and demonstrates coherence within several 100 matrix degrees of freedom in the vicinity." @default.
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- W2007782021 date "2009-03-23" @default.
- W2007782021 modified "2023-10-15" @default.
- W2007782021 title "Phase Sensitive Control of Vibronic Guest−Host Interaction: Br<sub>2</sub> in Ar Matrix" @default.
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- W2007782021 doi "https://doi.org/10.1021/jp900287m" @default.
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