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- W2007786118 abstract "The allylic acetoxylation of Δ5-steroids at C-4 by reaction with bromine and silver acetate has been shown to depend upon the nature of the C-3 substituent. 2H Labelling studies have shown that the reaction, which proceeds via the 5α,6β-dibromide, involves the trans diaxial elimination of a 4β-proton to form a Δ4-6β-bromide which then undergoes an SN2′ displacement by the incoming acetate assisted by the silver ion." @default.
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- W2007786118 date "1984-01-01" @default.
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- W2007786118 title "Allylic acetoxylation of Δ5-steroids at C-4" @default.
- W2007786118 doi "https://doi.org/10.1039/p19840002941" @default.
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