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- W2007790944 abstract "Summary The thermodynamics of higher-order transitions has caused “considerable discussion without notable agreement” 1). As controversies still exist it is worth while to give a more systematic outline then has been given up to now, especially as the experimental evidence is growing rapidly. This paper will be restricted to the study of systems in equilibrium, consisting of one component and two phases and one type of work only. The actual occurrence of the systems studied will play a minor role only. Taylor-series of the Gibbs' functions will be applied systematically to study the contact relations between the thermodynamic potentials. It will be shown that mathematically second order lines are a much more “exceptional” state of affairs than isolated second or higher order points on first order lines. The notion of double-point will be introduced and an application mentioned. As a by-product several relations involving higher-order-derivatives of transition-lines are found." @default.
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- W2007790944 date "1955-01-01" @default.
- W2007790944 modified "2023-09-27" @default.
- W2007790944 title "Thermodynamics of two-phase-systems" @default.
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- W2007790944 doi "https://doi.org/10.1016/s0031-8914(55)90059-8" @default.
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