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• W2007802969 abstract "Trichosporon sp. (TSL), a newly found strain isolated from a locally fermented cottage cheese has been found to be highly stereoselective in the resolution of (S)-(+)-naproxen (ee >99%, E∼500) from the corresponding racemic methyl ester. The process of resolution using whole cells has been scaled up to multi-kg level. Optimization of experimental conditions including downstream processing at 80–100 g/L substrate concentration with >90% recovery has been achieved. Changes in the physical parameters such as the particle size of the substrate play an important role in the resolution kinetics. A new strain of Trichosporon sp. having high cell density in cultivation (>60 g dry cell mass L−1 in 14–16 h) is found to be sufficiently stable for two years in dry powder form at 5–8°C. The viability of the resolution process has been further improved by the development of a simple racemization process for the enriched (R)-(−)-ester." @default.
• W2007802969 created "2016-06-24" @default.
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• W2007802969 date "2003-08-01" @default.
• W2007802969 modified "2023-10-16" @default.
• W2007802969 title "Enzymatic resolution of naproxen" @default.
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• W2007802969 doi "https://doi.org/10.1016/s0957-4166(03)00492-0" @default.
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