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- W2007807729 abstract "Abstract Two new metal–organic frameworks {[Ni(L) 2 ] ·4H 2 O} n ( 1 ) and {[Co(L) 2 ]·4H 2 O} n ( 2 ) have been prepared by reactions of 3,5-di(pyridine-4-yl)benzoic acid (HL) with corresponding metal salt under solvothermal conditions, and characterized by single crystal and powder X-ray diffractions, IR, elemental and thermogravimetric analyses. 1 and 2 have the same 2-fold interpenetrating three-dimensional structure with ins topology and are porous frameworks upon desolvation. More importantly, the desolvated samples of 1 and 2 show high thermal stability, vapor adsorption of H 2 O, MeOH or EtOH, and high enthalpy for CO 2 adsorption and high selectivity for CO 2 over N 2 at 298 K, implying the potential application of the coordination polymers for capture and separation of CO 2 ." @default.
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- W2007807729 date "2013-05-01" @default.
- W2007807729 modified "2023-10-15" @default.
- W2007807729 title "Porous metal–organic frameworks with high stability and selective sorption for CO2 over N2" @default.
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- W2007807729 doi "https://doi.org/10.1016/j.micromeso.2013.01.020" @default.
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