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- W2007853670 abstract "The epitaxial growth of an adsorbed layer of NH 3 on top of chemisorbed CO on Ni(111) and Ni(110) surfaces was studied using ESDIAD. A strong interaction yielding an activation energy for NH 3 desorption of ∼12 kcal/mol was observed. This interaction, possibly involving hydrogen bonding, between the adsorbed NH 3 and adsorbed CO causes a tilting of the NH 3 molecules on the CO-covered Ni surfaces. For the NH 3 /CO/Ni(110) system, the two-fold symmetry of the underlying Ni substrate is transmitted through the CO spacer layer to the NH 3 overlayer. This symmetry transfer was not observed for the NH 3 /CO/Ni(111) system at the current resolution of our ESDIAD detection system." @default.
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- W2007853670 date "1987-01-01" @default.
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- W2007853670 title "The epitaxial formation of adsorbed multilayers as studied by ESDIAD: NH3 adsorption on top of chemisorbed CO on nickel crystal surfaces" @default.
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- W2007853670 doi "https://doi.org/10.1016/s0039-6028(87)81045-2" @default.
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