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- W2007862804 abstract "Abstract A simulation of the energy levels of Eu3+, 4f6, was done using a “small” matrix involving 387 states in the configuration and a “larger” matrix involving 671 states. The hamiltonian takes into account both free atom and crystal field parameters (CFPs). It is possible to reproduce fairly well the position of 5D0. A correlation can be made with the values of the second rank CFPs. The crystal field splittings of 5DJ (J = 1, 2, 3) cannot however be reproduced in numerous cases for which the CFPs are well-known from 7FJ studies and this is not apparently a truncation effect. It seems that there is a problem in coupling the three different 5D levels under the crystal field in the conventional approach. This may be connected to the similar difficulty in the splittings of 2H 11 2 of Nd3+ or 3K8 of Ho3+." @default.
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- W2007862804 date "1989-04-01" @default.
- W2007862804 modified "2023-09-24" @default.
- W2007862804 title "Computer simulation of the 5Dj levels of 4f6, Eu3+" @default.
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- W2007862804 doi "https://doi.org/10.1016/0022-5088(89)90025-8" @default.
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