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- W2007886171 abstract "Abstract The structure of glasses with composition x TiO 2 ·(65 − x ) P 2 O 5 ·35 CaO ( x = 0–30 mol%) has been studied and their glass transition temperature, Raman and NMR spectra have been analysed. For TiO 2 -free glass two phosphate species have been identified as Q 2 and Q 3 . Increasing TiO 2 content in glass compositions results in the disappearance of the Q 3 and Q 2 species and in the formation of, mainly, pyrophosphate structure, Q 1 . In calcium titanophosphate glass with higher TiO 2 content the structure consists of a distorted Ti octahedral linked to pyrophosphate unit through P–O–Ti bonds. In these glass series the structural cohesion increases with TiO 2 , although a depolymerization in the original P–O–P network occurs. The study of these glasses and the understanding of their structural characteristics can give a valuable contribution for the clarification of their degradation behaviour namely in biological environments." @default.
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- W2007886171 date "2010-04-01" @default.
- W2007886171 modified "2023-10-17" @default.
- W2007886171 title "Structural characterization of TiO2–P2O5–CaO glasses by spectroscopy" @default.
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- W2007886171 doi "https://doi.org/10.1016/j.jeurceramsoc.2009.11.001" @default.
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