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- W2007888981 abstract "Abstract The results of an initial kinetic study of the oxidation of Ru(bpy)32+ to Ru(bpy)33+ by Tl3+ ions, catalysed by a dispersion of RuO2·xH2O in 3 mol dm−3 HNO3, as a function of [Ru(bpy)32+], [Tl3+], [Tl+], [RuO2·xH2O] and temperature, are reported. The kinetics of Ru(bpy)32+ oxidation fit an electrochemical model of redox catalysis involving electron transfer between the two highly reversible redox couples, i.e. Ru(bpy)33+/Ru(bpy)32+ and Tl3+/Tl+, mediated by the dispersion of microelectrode particles of RuO2·xH2O. This work describes a rare example of reversible redox catalysis." @default.
- W2007888981 created "2016-06-24" @default.
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- W2007888981 date "1993-07-01" @default.
- W2007888981 modified "2023-09-24" @default.
- W2007888981 title "Oxidation of ruthenium(II) tris(2,2-bipyridine) ions by thallic ions, mediated by ruthenium dioxide hydrate: a classic example of reversible redox catalysis" @default.
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- W2007888981 doi "https://doi.org/10.1016/s0020-1693(00)85146-4" @default.
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