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- W2007923853 abstract "EPR and magnetic susceptibility measurements have been performed on (CuO·2V2O5)(1−x)[2B2O3·K2O] glasses with 0 ⩽ x ⩽ 40 mol. %. For x < 10 mol.%, both Cu2+ and V4+ ions are present mostly as the isolated species. The values of MO coefficients indicate a high covalent degree of the transition metal (TM)-oxygen bonds. Also, the EPR parameters suggest the presence of strong (TM)-oxygen bonds along the 0z axis, which lead to an octahedral (Oh) symmetry component at TM ions sites. In the case of 10 ⩽ x ⩽ 40 mol.%, the dipole-dipole and superexchange interactions occur between transition metal ions, which determine a broad resonance line at g ⋍ 2. The strong interactions between Cu2+ and V4+ ions give rise to the exchange coupled Cu2+ V4+ pairs in the studied glasses with x > 10 mol.% (y > 3.9 mol.%)." @default.
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- W2007923853 date "1984-10-01" @default.
- W2007923853 modified "2023-09-27" @default.
- W2007923853 title "The investigation of the magnetic interaction between Cu2+ and V4+ ions in x(CuO·2V2O5)(1 − x)[2B2O3·K2O] glasses" @default.
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- W2007923853 doi "https://doi.org/10.1016/0022-3093(84)90031-0" @default.
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