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- W2007930976 abstract "The first band in the vacuum ultraviolet photoelectron spectrum of the silyl radical, corresponding to the process SiH3 (X 1A′1) ← SiH3(X 2A1), has been observed with HeI radiation. Extensive vibrational fine structure associated with the SiH3+ deformation vibration was observed in this band and analysis of the structure gave a value of ω = 820 = 40 cm-1 for the out-of-plane deformation mode in the ion. The vertical and adiabatic ionization energies were measured as 8.74 = 0.01 eV and 8.14 ± 0.01 eV respectively and use of the latter value together with the established heat of formation of the silyl radical allows an improved heat of formation of SiH3-. ΔH2980 (SiH3-) to be derived as 980 ± 7 kJ mol−1." @default.
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- W2007930976 date "1983-11-01" @default.
- W2007930976 modified "2023-10-09" @default.
- W2007930976 title "Vacuum ultraviolet photoelectron spectroscopy of transient species. XVII. The SiH3(X 2A1) radical" @default.
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- W2007930976 doi "https://doi.org/10.1016/0301-0104(83)85339-7" @default.
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