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- W2007938276 abstract "The substitution reactions of nitrocyclohexanes 8, 9, 12 and 23 with various nucleophiles were studied and were found to proceed by the electron-transfer initiated SRN1 mechanism. Epimeric products were formed and the proportion of epimers under both thermodynamic and kinetic control normally reflected the bulk of the incoming nucleophile relative to the substituent which was present at the reaction site. In the reaction of 23 with relatively high concentrations of PhS− in HMPA the reaction proceeded with high stereoretention. The results of these reactions are discussed in terms of the stability of radical configuration and the rate and mode of radical anion dissociations and associations." @default.
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- W2007938276 date "1982-01-01" @default.
- W2007938276 modified "2023-10-11" @default.
- W2007938276 title "The stereochemistry of the SRN1 reaction in some cyclohexane derivatives" @default.
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- W2007938276 doi "https://doi.org/10.1016/0040-4020(82)80122-1" @default.
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