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• W2007942383 abstract "We have described the first successful application of a phosphite−oxazoline ligand library in the asymmetric Ir-catalyzed hydrogenation of several unfunctionalized olefins. The introduction of a bulky biaryl phosphite moiety in the ligand design is highly adventitious in the product outcome. By carefully selecting the ligand components, we obtained high activities (TOFs up to >1500 mol·(mol·h)−1 at 1 bar of H2) and enantioselectivities (ee values up to >99%) and, at the same time, show a broad scope for different substrate types. So, this is an exceptional ligand class that competes favorably with a few other ligand series that also provide high ee values for tri- and disubstituted substrate types." @default.
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• W2007942383 date "2008-05-16" @default.
• W2007942383 modified "2023-10-18" @default.
• W2007942383 title "Chiral Pyranoside Phosphite−Oxazolines: A New Class of Ligand for Asymmetric Catalytic Hydrogenation of Alkenes" @default.
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• W2007942383 doi "https://doi.org/10.1021/ja801706s" @default.
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