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- W2007957687 abstract "Nanocrystalline magnesium ferrite is synthesized by high-energy ball milling. The formation of nanocrystalline ferrite phase is observed after 3 h of milling and its content increases with milling time. The structural and microstructural evolution of the nanophase have been studied by X-ray powder diffraction and the Rietveld method. After 3 h of milling, ferrite phase (mixed spinel) nucleates from the starting α-Fe2O3–MgO solid solution. After 5 h of milling, a second ferrite phase (inverse spinel) with a larger lattice parameter emerges and its content grows in parallel with that of the mixed spinel matrix. After 11 h of milling, only a very small amount (∼3 wt.%) of the starting α-Fe2O3 remains unused. With increasing milling time the type of the cationic distribution over the tetrahedral and octahedral sites in the lattice of the nanocrystalline material changes from a mixed to inverse type. Microstructure characterization by HRTEM corroborates the findings of X-ray analysis." @default.
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- W2007957687 date "2005-09-01" @default.
- W2007957687 modified "2023-09-29" @default.
- W2007957687 title "Microstructure characterization and cation distribution of nanocrystalline magnesium ferrite prepared by ball milling" @default.
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- W2007957687 doi "https://doi.org/10.1016/j.matchemphys.2005.03.017" @default.
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