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• W2007965950 abstract "The preparation and characterization of multifunctional ZnO1−xNx (x ≤ 0.15) via a simple solution combustion method is reported. ZnO1−xNx exhibits visible light absorption, thermal stability, nanometer-/micrometer-sized triangular particles, and catalytic properties. X-ray diffraction studies of ZnO1−xNx demonstrate that the lattice oxygen in ZnO is replaced by nitrogen without any major change in the wurtzite structure; however, charge compensation occurs, because of interstitial Zn atoms, as well as oxygen vacancies. Microscopic studies reveal the dominance of nanometer- and micrometer-sized triangles of ZnO1−xNx. UV−visible and Raman spectra indicate a midgap state, derived from N 2p states, and direct Zn−N interaction, respectively. Secondary ion mass spectrometry studies show the presence of N and ZnN species in the bulk and support the direct Zn−N interaction. Electron paramagnetic resonance (EPR) studies indicate the presence of a small amount of defects. Photocatalytic decomposition of rhodamine B, and anisole acylation at room temperature, highlights the effectiveness of ZnO1−xNx to catalysis applications. The aforementioned multifunctional characteristics suggest that ZnO1−xNx might be used in place of conventional ZnO for better control and that it might be explored for further applications in catalysis and optoelectronics." @default.
• W2007965950 created "2016-06-24" @default.
• W2007965950 creator A5022117066 @default.
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• W2007965950 date "2008-12-19" @default.
• W2007965950 modified "2023-10-04" @default.
• W2007965950 title "Combustion Synthesis of Triangular and Multifunctional ZnO_1−<i>x</i>N_<i>x</i> (<i>x</i> ≤ 0.15) Materials" @default.
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• W2007965950 doi "https://doi.org/10.1021/cm803048h" @default.
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