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- W2007980869 abstract "The synthesis and spectroscopic and structure chemical properties of complexes with the ligands trans-2-pyrazol-1-ylcyclohexan-1-ol (1), cis-(1-amino)(2-pyrazol-1-yl)cyclohexane (2) and 2-pyrazol-1-ylcyclohexanonoxime (4) coordinated to a variety of first and second row transition metals are described. These new systems bear cycloalkane backbones, which give rise to rigid ligand arrangements at the metal centre. X-ray crystallographic investigations of the copper(II) complexes CuCl2(1)2·(H2O)2 (5e) and [Cu(1)2](CuCl4) (5f) proved the coordination of two different enantiomers of ligand 1 to one copper centre. Owing to their d9 configuration, both octahedrally coordinated metal centres show typical Jahn-Teller distortions with either loosely bound chloro ligands or bridging CuCl42− anions occupying the apical positions. The copper(II) complex [CuCl2(2)]2·(6) forms dimers in the solid state, wherein the trigonal bipyramidally coordinated Cu centres are linked by bridging chloro ligands." @default.
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- W2007980869 date "1998-01-01" @default.
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- W2007980869 title "Cycloalkanes as ligand backbones part 5 [1] coordination chemistry of trans-2-pyrazol-1-ylcyclohexan-1-ol and derivatives: synthesis, spectroscopic features and solid state structures of first and second row transition metal complexes" @default.
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- W2007980869 doi "https://doi.org/10.1016/s0277-5387(97)00499-3" @default.
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