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- W2007991644 abstract "Abstract Allylation and crotylation reactions of 2,3-anti-β-hydroxy-α-methyl aldehydes 10 and 11 with allyl and crotyltrifluorosilanes 2, 8 and 9 proceed with high selectivity via the bicyclic chelated transition states 3 and 30. In contrast, analogous allylation and crotylation reactions of the 2,3-syn-β-hydroxy-α-methyl aldehydes 12 and 13 with 2,8 and 9 are generally less selective and proceed preferentially by way of the normal Zimmerman-Traxler transition states 6 and 32." @default.
- W2007991644 created "2016-06-24" @default.
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- W2007991644 date "2010-06-13" @default.
- W2007991644 modified "2023-09-27" @default.
- W2007991644 title "ChemInform Abstract: Stereochemically Divergent Pathways for the Allylation and Crotylation Reactions of anti- and syn-β-Hydroxy-α-methyl Aldehydes with Allyl- and Crotyltrifluorosilanes." @default.
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- W2007991644 doi "https://doi.org/10.1002/chin.199934040" @default.
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