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- W2007991807 abstract "The Hg-CH4 van der Waals complex has been studied in a supersonic jet expansion, in transitions correlated with the 6 1S0→6 3P1 mercury transitions. Fuorescence excitation spectra and action spectra have been recorded to analyse the corresponding transitions X→A and X→B. Through isotopic substitution of methane with deuterated methane, the origin band is assigned, and the vibrations of the complex characterised in a simple quasi-diatomic fashion as stretching and bending motions of methane with respect to mercury. These motions correspond to the radial and angular potentials of the complex. Emission spectra from selected stretch levels in the A and B states have confirmed the vibrational quantum assignment and provided a full determination of the radial ground-state potential." @default.
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- W2007991807 date "1987-11-01" @default.
- W2007991807 modified "2023-09-29" @default.
- W2007991807 title "Potential characteristics of the mercury-methane van der Waals complex" @default.
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- W2007991807 doi "https://doi.org/10.1016/0009-2614(87)85014-5" @default.
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