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- W2007994146 abstract "Abstract Fluorinated naphthalene derivatives were prepared by Bergman cyclization of fluorinated benzo‐fused enediynes. This route provides access to the aromatic target compounds in a two‐step procedure from commercially available precursors, via a Sonogashira cross‐coupling and a subsequent, thermally initiated Bergman cyclization. Crystal structures of six fluorinated benzo‐enediynes and three fluorinated naphthalene derivatives display significant diversity in their molecular structures and in the crystal packing arrangements. The rather subtle structural change from di‐ to tetrafluorobenzo‐enediynes, as well as the variation in the terminal acetylene subunit led to different non‐covalent interactions in the solid state that ultimately govern their crystal structures." @default.
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- W2007994146 date "2011-04-19" @default.
- W2007994146 modified "2023-10-12" @default.
- W2007994146 title "Bergman Cyclization of Fluorinated Benzo‐Fused Enediynes to Naphthalene Derivatives: Syntheses and Structures" @default.
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- W2007994146 doi "https://doi.org/10.1002/ejoc.201001747" @default.
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