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- W2007997790 abstract "The surface of graphite was modified employing powder immersion reaction assisted coating (PIRAC) method. Graphite plates were immersed into Ti powder and annealed at 800–1000 °C. Crystalline iodine was admixed to Ti powder in order to accelerate the transfer of Ti atoms onto the graphite surface. As a result of interaction between Ti and graphite, continuous Ti carbide coatings were formed with a thin layer of stiochiometric TiC on the graphite substrate/coating interface and Ti-rich TiC1−x in the outer part of the coating with concentration of carbon decreasing towards the surface of the coating. The coating was found to grow by a parabolic law with the kinetic constant, k = 3.7 × 10−8 exp(−160,000/RT) m2/s, the process being controlled by diffusion along fast diffusion paths. At low iodine concentrations and short exposures the amount of admixed iodine affected the rate of titanium carbide coating growth. A kinetic model of the process of coating growth is proposed." @default.
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- W2007997790 date "2005-04-01" @default.
- W2007997790 modified "2023-10-08" @default.
- W2007997790 title "Formation of titanium carbide on graphite via powder immersion reaction assisted coating" @default.
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- W2007997790 doi "https://doi.org/10.1016/j.msea.2005.01.011" @default.
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