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• W2008013841 abstract "A full-potential linearized muffin-tin orbital calculation is presented of titanium-carbon systems in a variety of crystallographic forms. The calculated electronic structure, total energies, and equilibrium lattice constants are determined for the ground-state NaCl structure of TiC and for prototype superlattice structures, and these results are discussed in terms of the nature of bonding found in TiC. Similar calculations are also given for WC in two of these crystalline forms, and the differing ground-state structure and equilibrium lattice constants in these two carbide materials are related to the behavior of those metallic d states which are occupied in WC and unoccupied in TiC. The behavior of these one-electron states, which stabilize WC in a simple hexagonal form, is similar to the calculated behavior of associated states in the prototype superlattice Ti-C structures, and these states are found to play a similar role in determining the structural characteristics in these systems. Some of the properties and probable stability of the various crystalline forms are also discussed in terms of our results." @default.
• W2008013841 created "2016-06-24" @default.
• W2008013841 creator A5014642273 @default.
• W2008013841 creator A5087645799 @default.
• W2008013841 date "1989-03-15" @default.
• W2008013841 modified "2023-10-09" @default.
• W2008013841 title "Total energies and bonding for crystallographic structures in titanium-carbon and tungsten-carbon systems" @default.
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• W2008013841 doi "https://doi.org/10.1103/physrevb.39.4945" @default.
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