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• W2008029267 abstract "The novel organic tridentate ligand, 8-hydroxyquinoline-2-carbaldehyde-N-methylnitrone (HL), has been synthesized and used for the design of a metal–organic system capable of self-association. Interaction of the nitrone HL with nickel nitrate afforded the hydrogen nitronate complex [Ni(HL)(L)]2(NO3)2·7H2O, which was characterized by means of X-ray diffraction. The coordination environment of the metal atoms consists of four oxygen and two nitrogen atoms from neutral and anionic forms of the ligand. [Ni(HL)(L)]+ cations possess a set of self-complementary H-bond donor/acceptor sites and dimerize via strong hydrogen bonding (O⋯O 2.43, 2.45 Å) forming supramolecular dications [Ni(HL)(L)]22+. Dimerization occurs enantioselectively between [Ni(HL)(L)]+ moieties of the same chirality and the resulting dimeric ensemble is inherently chiral. The stability of the dimer is essentially influenced by stacking interactions between two pairs of aromatic frames." @default.
• W2008029267 created "2016-06-24" @default.
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• W2008029267 date "2001-04-01" @default.
• W2008029267 modified "2023-09-23" @default.
• W2008029267 title "Nickel(II) and tridentate 8-hydroxyquinoline-2-carbaldehyde-N-methylnitrone (HL): enantioselective association of octahedral [M(HL)(L)]+ moieties driven by strong hydrogen bonding" @default.
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• W2008029267 doi "https://doi.org/10.1016/s0277-5387(01)00710-0" @default.
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