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- W2008078048 abstract "The reaction of 1,1-diarylethylenes with tellurium tetrachloride gives dimers as well as adducts containing two molecules of the ethylenes bound to TeCl2. The u.v., i.r., n.m.r., and mass spectra of the adducts have been measured and the influence of temperature and solvent changes on the n.m.r. spectra has been studied. Several possible structures are proposed and discussed. The chlorine atoms in the adduct (Ph2CCH2)2TeCl2(IIa) can be exchanged for other halogen atoms. Various reactions of the adducts have been studied, in some of which the tellurium atom is retained in a σ-bonded bis-(2,2-diarylvinyl) telluride product while in others it is lost, yielding products derived from the 1,1-diarylethylene portion only." @default.
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- W2008078048 date "1971-01-01" @default.
- W2008078048 modified "2023-10-18" @default.
- W2008078048 title "Reaction of 1,1-diarylethylenes with tellurium halides" @default.
- W2008078048 doi "https://doi.org/10.1039/j39710003100" @default.
- W2008078048 hasPublicationYear "1971" @default.
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