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- W2008093968 abstract "The reaction of magnesium and oxygen atoms in argon, krypton, xenon and oxygen matrices at 20.4° K was studied by infrared spectroscopy between 200 and 4000 cm−1. The appearance of a band in the magnesium-oxygen stretching region, reproducible in all the matrices, indicates that reaction takes place. Oxygen-13 isotopic substitution suggests that the absorption is due to Mg3O3, whose formation is supported by the crystal structure of the solid phase. The force constants are calculated as fR = 2.3 mdyne/Å and Fϕ/R2 = 0.44 mdyne/Å assuming a planar six-membered ring of alternate magnesium and oxygen atoms with bond angles O-Mg-O 100° and Mg-O-Mg 140°." @default.
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- W2008093968 date "1973-12-01" @default.
- W2008093968 modified "2023-09-23" @default.
- W2008093968 title "Infrared spectroscopic evidence of the Mg3O3 molecule formed by reaction of magnesium and oxygen atoms in inert gas matrices at 20.4°K" @default.
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- W2008093968 doi "https://doi.org/10.1016/0022-2860(73)85134-8" @default.
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