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• W2008102967 abstract "The diiron complex [Fe2{μ-к1(O):η1(C):η3(C)–C(N(Me)(Xyl))C(H)C(Me)C(O)OMe}(μ-CO)(Cp)2] (2) has been obtained from the diiron bridging vinyliminium [Fe2{μ-η1:η3–C(Me)C(H)CN(Me)(Xyl)}(μ-CO)(CO)(Cp)2][SO3CF3] (1; Xyl = 2,5-C6H3Me2) upon treatment with NaH in the presence of CH2CCMe2, followed by chromatography on alumina with MeOH as eluent. The reaction consists in the incorporation of a methylcarboxylate unit, assembled from CO and MeO−, into the bridging vinyliminium ligand. The resulting complex 2 exhibits a C4 fragment bridging the two iron centres through the carbonyl oxygen atom and the allylidene moiety. The X-ray molecular structure of 2 has been determined." @default.
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• W2008102967 date "2011-04-01" @default.
• W2008102967 modified "2023-10-14" @default.
• W2008102967 title "Assembly and incorporation of a CO2Me group into a bridging vinyliminium ligand in a diiron complex" @default.
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• W2008102967 doi "https://doi.org/10.1016/j.jorganchem.2011.01.011" @default.
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