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• W2008103886 abstract "The far-i.r. spectra of Fe(1,10-phenanthroline)2X2 complexes (XCl−, Br−, N−3, NCO−, OAc−, CNO− and CN−) have been measured in the 600–140 cm−1 region. The metal—ligand stretching vibrations are dependent on the spin state of Fe(II). For the high-spin complexes (XCl−, Br−, N−3, NCO−, OAc−) the FN(phen) stretches are found at ∼225 cm−1 and the FeX stretches in the 325–180 cm−1 region. For the low-spin complexes (XCN−, CNO−) the FeN(phen) stretches are found at 350–395 cm−1 and the FeX stretches at 520–540 cm−1. The FeCN stretch in K4FeCN6 is assigned at 588 cm−1. The ligand bands are also altered by spin state change. Significant vibrational coupling is found when XCN−." @default.
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• W2008103886 date "1974-03-01" @default.
• W2008103886 modified "2023-09-23" @default.
• W2008103886 title "Far-infrared spectra of some Fe(1,10-phenanthroline) 2X2 complexes" @default.
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• W2008103886 doi "https://doi.org/10.1016/0584-8539(74)80199-6" @default.
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