FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2008113175> ?p ?o ?g. }

• W2008113175 endingPage "246" @default.
• W2008113175 startingPage "209" @default.
• W2008113175 abstract "Abstract Mononuclear rhodium(II) compounds reported in the literature are tabulated, classified according to functionality and placed in one of four stability categories. The reactions reported for mononuclear Rh(II) compounds are presented and grouped according to reactivity type: adduct formation, ligand dissociation and substitution, dimerization, disproportionation, oxidation and reduction. Observed reactivity is rationalized on the basis of the factors that influence stability. Ligands that are sufficiently bulky can protect the metal from external attack by all but the smallest reagent molecules. Polydentate ligands can protect the metal from external attack or can impose coordination environments that destabilize Rh(I) or Rh(III). Electronic features of ligands that withdraw electron density or delocalize the unpaired electron from the metal promote stability. Reactivity can also depend on whether the Rh(II) complex is four coordinate (15 electron), five coordinate (17 electron) or six coordinate (19 electron). Because conventional two-electron oxidative addition and reductive elimination processes are not possible for Rh(II), redox behavior is of special interest. Mechanisms proposed for unusual oxidation and CH activation behavior in some Rh(II) systems are presented. Factors giving rise to differences in reactivity between different classes of Rh(II) compounds are evaluated." @default.
• W2008113175 created "2016-06-24" @default.
• W2008113175 creator A5035979033 @default.
• W2008113175 date "1996-01-01" @default.
• W2008113175 modified "2023-09-24" @default.
• W2008113175 title "Reactivity of mononuclear rhodium(II) compounds" @default.
• W2008113175 cites W104972133 @default.
• W2008113175 cites W1482092411 @default.
• W2008113175 cites W1567392545 @default.
• W2008113175 cites W1581321797 @default.
• W2008113175 cites W1963773943 @default.
• W2008113175 cites W1963918641 @default.
• W2008113175 cites W1965661584 @default.
• W2008113175 cites W1965677675 @default.
• W2008113175 cites W1965925118 @default.
• W2008113175 cites W1966179103 @default.
• W2008113175 cites W1967523563 @default.
• W2008113175 cites W1968588096 @default.
• W2008113175 cites W1968765690 @default.
• W2008113175 cites W1969040089 @default.
• W2008113175 cites W1969080822 @default.
• W2008113175 cites W1970902840 @default.
• W2008113175 cites W1972443043 @default.
• W2008113175 cites W1973642764 @default.
• W2008113175 cites W1973723982 @default.
• W2008113175 cites W1974727789 @default.
• W2008113175 cites W1975858139 @default.
• W2008113175 cites W1976315574 @default.
• W2008113175 cites W1976331682 @default.
• W2008113175 cites W1978139555 @default.
• W2008113175 cites W1979253462 @default.
• W2008113175 cites W1979951893 @default.
• W2008113175 cites W1980503721 @default.
• W2008113175 cites W1980834614 @default.
• W2008113175 cites W1982307538 @default.
• W2008113175 cites W1985226046 @default.
• W2008113175 cites W1985608996 @default.
• W2008113175 cites W1986354168 @default.
• W2008113175 cites W1986399803 @default.
• W2008113175 cites W1987508434 @default.
• W2008113175 cites W1988859795 @default.
• W2008113175 cites W1988950455 @default.
• W2008113175 cites W1989978895 @default.
• W2008113175 cites W1990133375 @default.
• W2008113175 cites W1991693204 @default.
• W2008113175 cites W1991965699 @default.
• W2008113175 cites W1993370319 @default.
• W2008113175 cites W1993662273 @default.
• W2008113175 cites W1996170888 @default.
• W2008113175 cites W1997122297 @default.
• W2008113175 cites W1997412481 @default.
• W2008113175 cites W1998795452 @default.
• W2008113175 cites W1998930615 @default.
• W2008113175 cites W1999024833 @default.
• W2008113175 cites W1999365804 @default.
• W2008113175 cites W2001546636 @default.
• W2008113175 cites W2004058751 @default.
• W2008113175 cites W2004162065 @default.
• W2008113175 cites W2004447859 @default.
• W2008113175 cites W2005341329 @default.
• W2008113175 cites W2005508085 @default.
• W2008113175 cites W2005953747 @default.
• W2008113175 cites W2010329852 @default.
• W2008113175 cites W2010956848 @default.
• W2008113175 cites W2014692497 @default.
• W2008113175 cites W2015143184 @default.
• W2008113175 cites W2015164927 @default.
• W2008113175 cites W2015784886 @default.
• W2008113175 cites W2015949231 @default.
• W2008113175 cites W2018714475 @default.
• W2008113175 cites W2018781751 @default.
• W2008113175 cites W2019035295 @default.
• W2008113175 cites W2020873683 @default.
• W2008113175 cites W2024468111 @default.
• W2008113175 cites W2024611929 @default.
• W2008113175 cites W2027159311 @default.
• W2008113175 cites W2027708658 @default.
• W2008113175 cites W2030470301 @default.
• W2008113175 cites W2030670560 @default.
• W2008113175 cites W2032771636 @default.
• W2008113175 cites W2033597814 @default.
• W2008113175 cites W2033875671 @default.
• W2008113175 cites W2036256576 @default.
• W2008113175 cites W2037163062 @default.
• W2008113175 cites W2038266452 @default.
• W2008113175 cites W2038514401 @default.
• W2008113175 cites W2038556831 @default.
• W2008113175 cites W2039424560 @default.
• W2008113175 cites W2043306988 @default.
• W2008113175 cites W2043628299 @default.
• W2008113175 cites W2044413824 @default.
• W2008113175 cites W2048299367 @default.
• W2008113175 cites W2048460550 @default.
• W2008113175 cites W2048682193 @default.
• W2008113175 cites W2048761312 @default.
• W2008113175 cites W2051234031 @default.
• W2008113175 cites W2052907048 @default.
• W2008113175 cites W2055094459 @default.

• next