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• W2008162532 abstract "The synthesis, electronic absorption, infrared and 13 C NMR spectra, and electrochemistry of [Cr(CO) 4 ]dpp and [W(CO) 4 ]dpp (dpp = 2,3-bis(2-pyridyl)pyrazine) are reported. Electronic absorption spectra in different solvents show solvatochromic behavior and indicate the metal to ligand charge transfer (MLCT) excited state is lower in energy than the ligand field (LF) excited state. Electrochemical results show the [Cr(CO) 4 ]dpp complex undergoes semi-reversible one electron oxidation, while [W(CO) 4 ]dpp undergoes irreversible one electron oxidation. 13 C NMR spectra of both complexes show all carbons in the metal-bound dpp ring shift downfield. The amount of downfield shift for the series [M(CO) 4 ]dpp (M = Cr, Mo, W) is interpreted as indicating better M dπ → dpp pπ backbonding occurs for Mo and W than for Cr." @default.
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• W2008162532 date "1987-01-01" @default.
• W2008162532 modified "2023-09-26" @default.
• W2008162532 title "Synthesis and characterization of chromium and tungsten tetracarbonyl bound to the bridging ligand 2,3-bis(2-pyridyl)pyrazine (dpp)" @default.
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• W2008162532 doi "https://doi.org/10.1016/s0277-5387(00)80769-x" @default.
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