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- W2008164513 abstract "The reactions of 1,5-dimethyl- and 1,3,5-trimethyl-6-methylenetricyclo[3.2.1.02,7]oct-3-en-8-one with vinylmagnesium bromide at 0 °C afforded 1,5-dimethyl- and 1,3,5-trimethyl-8-vinyl-6-methylenetricyclo[3.2.1.02,7]oct-3-en-8-ol, respectively. The thermal rearrangements of IIa,b and their alkoxybromomagnesium afforded 1,5-dimethyl or 1,3,5-trimethylbenzocyclohepten-6-one. It is suggested that the pathways involve an oxy-Cope rearrangement and the subsequent hydrogen migrations." @default.
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- W2008164513 date "1980-09-01" @default.
- W2008164513 modified "2023-10-09" @default.
- W2008164513 title "Thermal Rearrangements of 1,5-Dimethyl- and 1,3,5-Trimethyl-8-vinyl-6-methylenetricyclo[3.2.1.0<sup>2,7</sup>]oct-3-en-8-ol and Their Alkoxides" @default.
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- W2008164513 doi "https://doi.org/10.1246/bcsj.53.2683" @default.
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