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- W2008204087 abstract "The EPR spectra of crystals of CsMg${mathrm{Cl}}_{3}$, CsMg${mathrm{Br}}_{3}$, and CsCd${mathrm{Br}}_{3}$ doped with ${mathrm{Gd}}^{3+}$ are dominated by resonances arising from weakly coupled pairs. The host materials all adopt the linear-chain CsNi${mathrm{Cl}}_{3}$ structure. The exchange interactions between the ${mathrm{Gd}}^{3+}$ ions within the pairs are antiferromagnetic but extremely weak. At room temperature, the exchange parameter $J$ for the pair in CsMg${mathrm{Cl}}_{3}$, CsMg${mathrm{Br}}_{3}$, and CsCd${mathrm{Br}}_{3}$ is equal to +0.00107, +0.00080, and +0.00068 ${mathrm{cm}}^{ensuremath{-}1}$, respectively. The pairs consist of two ${mathrm{Gd}}^{3+}$ ions associated with a ${mathrm{Mg}}^{2+}$ or ${mathrm{Cd}}^{2+}$ ion vacancy. The unusual stability of this type of pair apparently arises from the strict charge-compensation requirement of the linear-chain $mathrm{Cs}M{X}_{3}$ lattice." @default.
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- W2008204087 title "EPR spectra of magnetically coupled pairs of G<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant=normal>d</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>ions in crystals of CsMg<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Cl</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></…" @default.
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- W2008204087 doi "https://doi.org/10.1103/physrevb.16.4756" @default.
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