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- W2008292009 abstract "A multitude of natural processes and technical applications require our ability to provide a reliable prediction of crystal surface reactivity. During the last decades, the detailed analysis of crystal surface reactions revealed the existence of intrinsic variability in surface reactivity. This reactivity acts in addition to extrinsic factors, such as inhibitors, background electrolytes, or pH variations. The nature of this intrinsic variability is poorly understood. In any case, it must represent complex energetic contributions from and interactions between reacting mineral surfaces and dissolved and particulate materials in the fluid. Consequently, single rate constants and homogeneous surface area normalization are problematic constraints for the explanation and prediction of surface reactions of both, natural and artificial materials. Here, we review various aspects of intrinsic variability of crystal surface reactivity from experimental and modeling results including the fundamental role of microscopic kink site distribution. Important reaction processes include crystal dissolution and sorption of small particles, i.e., nanoparticles and colloids. A key means of understanding these variations lies in understanding the relationship between surface energy distribution and surface roughness. Rough surfaces are well-known to control the retention of colloids and nanoparticles under unfavorable adsorption conditions. This review provides an integrated view on an important feedback process that includes surface reactivity, kink site distribution, surface roughness, particle retention, and surface inhibition as critical components. Also, we review briefly the methods used to quantify surface roughness variability over a wide range of scales. It is our goal to highlight the multiple facets that may both reflect or influence the intrinsic variability of reactions over time." @default.
- W2008292009 created "2016-06-24" @default.
- W2008292009 creator A5015023006 @default.
- W2008292009 creator A5053354102 @default.
- W2008292009 creator A5060000094 @default.
- W2008292009 creator A5073021685 @default.
- W2008292009 date "2014-04-01" @default.
- W2008292009 modified "2023-10-14" @default.
- W2008292009 title "Variability of crystal surface reactivity: What do we know?" @default.
- W2008292009 cites W1553630333 @default.
- W2008292009 cites W1607832304 @default.
- W2008292009 cites W1625864106 @default.
- W2008292009 cites W1643676121 @default.
- W2008292009 cites W1963610272 @default.
- W2008292009 cites W1964175533 @default.
- W2008292009 cites W1964822293 @default.
- W2008292009 cites W1965441971 @default.
- W2008292009 cites W1965637810 @default.
- W2008292009 cites W1968171600 @default.
- W2008292009 cites W1968282888 @default.
- W2008292009 cites W1969007482 @default.
- W2008292009 cites W1969203660 @default.
- W2008292009 cites W1969302318 @default.
- W2008292009 cites W1969324628 @default.
- W2008292009 cites W1971763845 @default.
- W2008292009 cites W1973669797 @default.
- W2008292009 cites W1974348078 @default.
- W2008292009 cites W1974651819 @default.
- W2008292009 cites W1974836081 @default.
- W2008292009 cites W1975098322 @default.
- W2008292009 cites W1976622365 @default.
- W2008292009 cites W1978103685 @default.
- W2008292009 cites W1978256212 @default.
- W2008292009 cites W1978356314 @default.
- W2008292009 cites W1979978358 @default.
- W2008292009 cites W1980918731 @default.
- W2008292009 cites W1981359870 @default.
- W2008292009 cites W1982262378 @default.
- W2008292009 cites W1983316441 @default.
- W2008292009 cites W1986082905 @default.
- W2008292009 cites W1986589104 @default.
- W2008292009 cites W1987285774 @default.
- W2008292009 cites W1989694939 @default.
- W2008292009 cites W1990156388 @default.
- W2008292009 cites W1990250430 @default.
- W2008292009 cites W1991941953 @default.
- W2008292009 cites W1992191754 @default.
- W2008292009 cites W1992540355 @default.
- W2008292009 cites W1993025030 @default.
- W2008292009 cites W1993145840 @default.
- W2008292009 cites W1996770263 @default.
- W2008292009 cites W1996896750 @default.
- W2008292009 cites W1997863197 @default.
- W2008292009 cites W1999165439 @default.
- W2008292009 cites W2001390902 @default.
- W2008292009 cites W2001750738 @default.
- W2008292009 cites W2002242221 @default.
- W2008292009 cites W2003618881 @default.
- W2008292009 cites W2007390370 @default.
- W2008292009 cites W2008717173 @default.
- W2008292009 cites W2008981258 @default.
- W2008292009 cites W2011154313 @default.
- W2008292009 cites W2011254969 @default.
- W2008292009 cites W2011678056 @default.
- W2008292009 cites W2012635927 @default.
- W2008292009 cites W2014037387 @default.
- W2008292009 cites W2016148083 @default.
- W2008292009 cites W2017178401 @default.
- W2008292009 cites W2018283520 @default.
- W2008292009 cites W2019373689 @default.
- W2008292009 cites W2020496176 @default.
- W2008292009 cites W2023443859 @default.
- W2008292009 cites W2024608670 @default.
- W2008292009 cites W2025011021 @default.
- W2008292009 cites W2025017406 @default.
- W2008292009 cites W2025555033 @default.
- W2008292009 cites W2027692529 @default.
- W2008292009 cites W2027987247 @default.
- W2008292009 cites W2029492414 @default.
- W2008292009 cites W2030081332 @default.
- W2008292009 cites W2032580073 @default.
- W2008292009 cites W2034974040 @default.
- W2008292009 cites W2036278155 @default.
- W2008292009 cites W2039338192 @default.
- W2008292009 cites W2040655719 @default.
- W2008292009 cites W2042331662 @default.
- W2008292009 cites W2043843726 @default.
- W2008292009 cites W2046235445 @default.
- W2008292009 cites W2046344198 @default.
- W2008292009 cites W2051028254 @default.
- W2008292009 cites W2051819960 @default.
- W2008292009 cites W2052879066 @default.
- W2008292009 cites W2055021136 @default.
- W2008292009 cites W2055414831 @default.
- W2008292009 cites W2055675204 @default.
- W2008292009 cites W2058282216 @default.
- W2008292009 cites W2058409890 @default.
- W2008292009 cites W2058679923 @default.