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- W2008306441 abstract "Variation of the number of crosslinks in polyvinylethylene (PVE) networks has a marked effect on the ${T}_{g}$-normalized temperature dependence (``fragility'') of the segmental relaxation times, even though the local chemical environment of virtually all repeat units is unchanged. Since the heat-capacity increment at ${T}_{g}$ is a decreasing function of the number of crosslinks, there is an inverse correlation between fragility and the heat-capacity difference between PVE's glassy and liquid states. This result is opposite to expectations based on an energy landscape interpretation of fragility." @default.
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- W2008306441 title "Test of the energy landscape interpretation of fragility in polymers" @default.
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