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- W2008331366 abstract "A fluorescent photoinduced electron transfer (PET) sensor (3) that consists of 1-aza-18-crown-6 and a 1-naphthyl pendant shows a fluorescent increase with bivalent metal ions and a fluorescent decrease with monovalent metal ions. (1)H and (13)C NMR analyses of this 1:1 complexation behavior revealed that Ba(2+) strongly coordinates with the azacrown nitrogen to cause a dramatic decrease in the intramolecular charge-transfer character. In addition, it was suggested that not only the metal ion-dependent coordinated structure of the resulting complex but also the interaction between the thiocyanate anion and the naphthyl group play a role in controlling the extent of the emission-intensity increase and decrease that was observed in the presence of a given metal salt." @default.
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- W2008331366 date "1999-01-05" @default.
- W2008331366 modified "2023-09-22" @default.
- W2008331366 title "Synthesis and complexation behavior of N-(1-naphthylmethyl)-1,4,7,10,13-pentaoxa-16-azacyclooctadecane" @default.
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- W2008331366 doi "https://doi.org/10.1016/s0039-9140(98)00229-x" @default.
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