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• W2008335020 abstract "Development of promising battery systems is being intensified to fulfil the needs of long-driving-ranged electric vehicles. The successful candidates for new generation batteries should have higher energy densities than those of currently used batteries and reasonable rechargeability. Here we report that aqueous lithium-iodine batteries based on the triiodide/iodide redox reaction show a high battery performance. By using iodine transformed to triiodide in an aqueous iodide, an aqueous cathode involving the triiodide/iodide redox reaction in a stable potential window avoiding water electrolysis is demonstrated for lithium-iodine batteries. The high solubility of triiodide/iodide redox couples results in an energy density of ~ 0.33 kWh kg−1, approximately twice that of lithium-ion batteries. The reversible redox reaction without the formation of resistive solid products promotes rechargeability, demonstrating 100 cycles with negligible capacity fading. A low cost, non-flammable and heavy-metal-free aqueous cathode can contribute to the feasibility of scale-up of lithium-iodine batteries for practical energy storage. Aqueous lithium batteries can store more energy because of their high ionic conductivity compared with the all-solid-state or non-aqueous electrolyte based counterparts. Zhao et al. report a large energy storage density by using safe and low-cost triiodide/iodide redox reaction in an aqueous cathode." @default.
• W2008335020 created "2016-06-24" @default.
• W2008335020 creator A5016883560 @default.
• W2008335020 creator A5042947574 @default.
• W2008335020 creator A5063790278 @default.
• W2008335020 date "2013-05-21" @default.
• W2008335020 modified "2023-10-02" @default.
• W2008335020 title "High-performance rechargeable lithium-iodine batteries using triiodide/iodide redox couples in an aqueous cathode" @default.
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• W2008335020 doi "https://doi.org/10.1038/ncomms2907" @default.
• W2008335020 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23695690" @default.
• W2008335020 hasPublicationYear "2013" @default.
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