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- W2008346775 abstract "Methyl 3-azido-3-deoxy-α and β-D-xylopyranoside are prepared. The oxidation of the 2-O-benzoylated derivative of the above-mentioned α-anomer with the Pfitzner-Moffatt reagent leads to the facile elimination of the elements of benzoic acid and the formation of the 4-azido derivative of 5,6-dihydro-α-pyran-5-one. The 3-ethoxycarbonylamido derivative obtained from the above mentioned 3-azido derivative is oxidized similarly to afford the 4-ethoxycarbonylamido derivative of 5,6-dihydro-α-pyran-5-one. The mechanisms of these elimination reactions are discussed." @default.
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- W2008346775 date "1970-02-01" @default.
- W2008346775 modified "2023-10-09" @default.
- W2008346775 title "Studies on Aminosugars. XXIV. The Facile Elimination of the Derivatives of a Pyranosid-4-ulose" @default.
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- W2008346775 doi "https://doi.org/10.1246/bcsj.43.531" @default.
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