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- W2008357404 abstract "Die Mischkristallreihe NaClO3NaBrO3 wurde nach verschiedenen präparativen Verfahren hergestellt und mit Hilfe analytischer und röntgenographischer Methoden kontrolliert. Die Infrarotspektren der reinen Halogenate und der Mischkristalle wurden bei Zimmertemperatur und bei −196°C aufgenommen. Der Vergleich der Spektren des reinen NaClO3 und der Mischkristalle mit geringer Chloratkonzentration im Bromat-Wirtskristall ermöglichten den Machweis intermolekularer Kopplung im NaClO3. Es zeigte sich, daß die Entkopplung isolierter Molekeln im Mischkristall beim Einbau von Bromationen in den Chlorat-Wirtskristall von zusätzlichen Effekten überlagert wird. Investigation of the Effect of Vibrational Coupling in Sodium Chlorate and Bromate by Means of Anion-Mixed Crystals Mixed crystals of the system NaClO3NaBrO3 were prepared in different ways and investigated by analytical and X-ray methods. The infrared spectra of the pure halogenates and the mixed crystals were recorded by room temperature and by −196°C. Comparison of the spectra of pure NaClO3 and the mixed crystal with low chlorate concentration in a bromate host crystal permits evidence of the intermoleculare coupling in NaClO3. It is shown that reversal of coupling in mixed crystals in the case of bromate in a chlorate host crystal is superposed by additional effects." @default.
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- W2008357404 date "1973-06-01" @default.
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- W2008357404 title "Untersuchung der Schwingungskopplung in Natriumchlorat und Natriumbromat mit Hilfe der Anionen-Mischkristalle" @default.
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- W2008357404 doi "https://doi.org/10.1002/zaac.19733990104" @default.
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