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- W2008366838 abstract "Artemether is an important widely used derivative of artemisinin. On a glassy carbon electrode, artemether undergoes an entirely irreversi le reduction at ca. -1.18 V Hemin can catalyze the reduction of artemether as it catalyzes that of artemisinin. In the presence of concentrations of hemin as low as 8 X 10 8 M, the reduction happens at -0.54 V, reducing the cathodic overpotential ca. 640 mV Ethylenediaminetetraacetic acid (EDTA)-Fe(III) complex also catalyzes the reduction of artemether while reducing the cathodic overpotential about 680 mV; but a concentration of at least 4 x 10 4 M was required. Experiments suggested artemether might undergo the identical antimalarial mechanism as artemisinin. All these further confirm the important role of hemin in the mechanism of action of artemisinin-type drugs." @default.
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- W2008366838 date "1997-06-01" @default.
- W2008366838 modified "2023-09-27" @default.
- W2008366838 title "Electrocatalytic Reduction of Artemether by Hemin" @default.
- W2008366838 doi "https://doi.org/10.1149/1.1837716" @default.
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