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- W2008381623 abstract "Infrared absorption spectra are compared with palladium carbonyl clusters encaged in zeolites Y and 5A. Marked differences are attributed, in terms of a dynamic model, to different sizes of the α-cage windows which control migration of primary clusters. Under conditions in which Pd13(C0)x clusters prevail in zeolite Y, Pd6(C0)x dominates the IR spectrum in 5A. Higher reduction temperatures cause formation of larger particles in zeolite Y, but in 5A the small window size prevents particle growth. Whereas doubly-bridged CO is abundant on Pd13 carbonyls in zeolite Y, terminal and triply-bridged CO prevail in Pd6(CO)x, as they do in Rh6(C0)16. Peak positions indicate different extents of electron deficiency. Marked color changes of calcined, reduced and CO-treated samples further illustrate the electronic interaction of Pd ions and clusters with the zeolite matrix." @default.
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- W2008381623 date "1991-08-01" @default.
- W2008381623 modified "2023-10-15" @default.
- W2008381623 title "FTIR study of novel Pd6 carbonyl clusters encaged in zeolite 5A" @default.
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- W2008381623 doi "https://doi.org/10.1016/0304-5102(91)80047-7" @default.
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