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- W2008485844 abstract "Abstract Various unsaturated peroxidic compounds have been prepared, characterized and inductively decomposed in various solvents to afford the corresponding oxiranes. The reaction proceeded by a radical chain mechanism and was initiated either by thermolysis of added t -butyl peracetate at 110°C or AIBN at 80°C, or by autoxidation of BEt 3 at 20°C. The studied peroxyderivatives were designed to generate oxyl radicals reacting either by isomerization ( e.g. intramolecular 1,5-hydrogen atom transfer, cyclization or β-scission of a cyclic structure), fragmentation or hydrogen atom transfer to solvents to yield functional alkyl radicals." @default.
- W2008485844 created "2016-06-24" @default.
- W2008485844 creator A5070693164 @default.
- W2008485844 date "1997-02-01" @default.
- W2008485844 modified "2023-09-26" @default.
- W2008485844 title "Synthesis of methacrylic-type peroxidic compounds and study of their homolytic induced decomposition in solution" @default.
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- W2008485844 doi "https://doi.org/10.1016/s0040-4020(96)01180-5" @default.
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