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- W2008547574 abstract "„Next to nothing is known about how fullerenes actually grow and form”︁. Dieser Satz wurde erst im Frühjahr publiziert, doch wenig später brachte eine Reihe von Arbeiten von Bowers et al. viel Licht in dieses Dunkel. Danach entstehen bei der Graphitverdampfung über einzelne C‐Atome primär C n + ‐Cluster, die als lineare (C + 5 ‐C 10 + ), monocyclische (C + 7 ‐C + 28 ) und planar‐bicyclische Kationen (C + 21 bis ca. C + 50 ) vorliegen: ab C + 30 gibt es auch Fullerene. Die wichtigste neue Erkenntnis ist nun. daß die mono‐ und bicyclischen C + n ‐Spezies bei weiterer Energiezufuhr direkt zu Fullerenen isomerisieren; zur „Abkühlung”︁ der „heißen”︁ Fullerene werden C 1 ‐, C 2 ‐ oder C 3 ‐Bausteine abgespalten." @default.
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- W2008547574 date "1993-10-01" @default.
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- W2008547574 title "Mechanismuds der Fulleren-Entsehung" @default.
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