Matches in SemOpenAlex for { <https://semopenalex.org/work/W2008550166> ?p ?o ?g. }
- W2008550166 endingPage "11068" @default.
- W2008550166 startingPage "11058" @default.
- W2008550166 abstract "Hydrogen-bonding interactions play an important role in many chemical and biological systems. Fluorine acting as a hydrogen-bond acceptor in intermolecular and intramolecular interactions has been the subject of many controversial discussions and there are different opinions about it. Recently, we have proposed a correlation between the propensity of fluorine to be involved in hydrogen bonds and its 19F NMR chemical shift. We now provide additional experimental and computational evidence for this correlation. The strength of hydrogen-bond complexes involving the fluorine moieties CH2F, CHF2, and CF3 was measured and characterized in simple systems by using established and novel NMR methods and compared to the known hydrogen-bond complex formed between acetophenone and p-fluorophenol. Implications of these results for 19F NMR screening are analyzed in detail. Computed values of the molecular electrostatic potential at the different fluorine atoms and the analysis of the electron density topology at bond critical points correlate well with the NMR results." @default.
- W2008550166 created "2016-06-24" @default.
- W2008550166 creator A5009428532 @default.
- W2008550166 creator A5010163062 @default.
- W2008550166 creator A5072319898 @default.
- W2008550166 date "2014-07-17" @default.
- W2008550166 modified "2023-10-05" @default.
- W2008550166 title "Fluorine as a Hydrogen-Bond Acceptor: Experimental Evidence and Computational Calculations" @default.
- W2008550166 cites W1963667263 @default.
- W2008550166 cites W1965516720 @default.
- W2008550166 cites W1965546181 @default.
- W2008550166 cites W1971911697 @default.
- W2008550166 cites W1978796282 @default.
- W2008550166 cites W1982018428 @default.
- W2008550166 cites W1983401069 @default.
- W2008550166 cites W1993988570 @default.
- W2008550166 cites W1994724199 @default.
- W2008550166 cites W1995735030 @default.
- W2008550166 cites W1999350919 @default.
- W2008550166 cites W1999404597 @default.
- W2008550166 cites W2001845444 @default.
- W2008550166 cites W2002352328 @default.
- W2008550166 cites W2005219826 @default.
- W2008550166 cites W2011204079 @default.
- W2008550166 cites W2015083330 @default.
- W2008550166 cites W2030619607 @default.
- W2008550166 cites W2032525140 @default.
- W2008550166 cites W2033043158 @default.
- W2008550166 cites W2033803996 @default.
- W2008550166 cites W2035185380 @default.
- W2008550166 cites W2035901399 @default.
- W2008550166 cites W2037558289 @default.
- W2008550166 cites W2040127097 @default.
- W2008550166 cites W2044125291 @default.
- W2008550166 cites W2048254503 @default.
- W2008550166 cites W2051469879 @default.
- W2008550166 cites W2054475133 @default.
- W2008550166 cites W2054786897 @default.
- W2008550166 cites W2054975178 @default.
- W2008550166 cites W2055168001 @default.
- W2008550166 cites W2055546038 @default.
- W2008550166 cites W2060011480 @default.
- W2008550166 cites W2061957367 @default.
- W2008550166 cites W2063915017 @default.
- W2008550166 cites W2073080195 @default.
- W2008550166 cites W2074490799 @default.
- W2008550166 cites W2075730622 @default.
- W2008550166 cites W2080917667 @default.
- W2008550166 cites W2085332552 @default.
- W2008550166 cites W2086951662 @default.
- W2008550166 cites W2098587560 @default.
- W2008550166 cites W2104919283 @default.
- W2008550166 cites W2114247306 @default.
- W2008550166 cites W2116087305 @default.
- W2008550166 cites W2118096932 @default.
- W2008550166 cites W2127597837 @default.
- W2008550166 cites W2132546405 @default.
- W2008550166 cites W2144869962 @default.
- W2008550166 cites W2166173570 @default.
- W2008550166 cites W2174286721 @default.
- W2008550166 cites W2320217038 @default.
- W2008550166 cites W2323434934 @default.
- W2008550166 cites W2334483169 @default.
- W2008550166 cites W2950630380 @default.
- W2008550166 cites W2951280254 @default.
- W2008550166 cites W2979092913 @default.
- W2008550166 cites W4254187329 @default.
- W2008550166 cites W602958923 @default.
- W2008550166 doi "https://doi.org/10.1002/chem.201402858" @default.
- W2008550166 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25044441" @default.
- W2008550166 hasPublicationYear "2014" @default.
- W2008550166 type Work @default.
- W2008550166 sameAs 2008550166 @default.
- W2008550166 citedByCount "142" @default.
- W2008550166 countsByYear W20085501662014 @default.
- W2008550166 countsByYear W20085501662015 @default.
- W2008550166 countsByYear W20085501662016 @default.
- W2008550166 countsByYear W20085501662017 @default.
- W2008550166 countsByYear W20085501662018 @default.
- W2008550166 countsByYear W20085501662019 @default.
- W2008550166 countsByYear W20085501662020 @default.
- W2008550166 countsByYear W20085501662021 @default.
- W2008550166 countsByYear W20085501662022 @default.
- W2008550166 countsByYear W20085501662023 @default.
- W2008550166 crossrefType "journal-article" @default.
- W2008550166 hasAuthorship W2008550166A5009428532 @default.
- W2008550166 hasAuthorship W2008550166A5010163062 @default.
- W2008550166 hasAuthorship W2008550166A5072319898 @default.
- W2008550166 hasConcept C112887158 @default.
- W2008550166 hasConcept C116447816 @default.
- W2008550166 hasConcept C121332964 @default.
- W2008550166 hasConcept C139286075 @default.
- W2008550166 hasConcept C147597530 @default.
- W2008550166 hasConcept C159467904 @default.
- W2008550166 hasConcept C166950319 @default.
- W2008550166 hasConcept C178213299 @default.
- W2008550166 hasConcept C178790620 @default.
- W2008550166 hasConcept C185592680 @default.