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- W2008553789 abstract "When alkaline earth ions in borates, phosphates or borophosphates [SrB4O7, SrB6O10, BaB8O13, MBPO5 (M=Ca,Sr)] are substituted partially and aliovalently by trivalent rare earth ions such as Sm3+, Eu3+, these rare earth ions can be reduced to divalent state by the produced negative charge vacancy VM″. The matrices must have appropriate structure containing a rigid three-dimensional network of tetragonal AO4 groups (A=B,P). These groups can surround and isolate the produced divalent RE2+ ions from the reaction with oxygen. Therefore, this reduction reaction can be carried out even in air at high temperature. The produced divalent rare earth ions can be detected by luminescence and XANES methods and their spectroscopic properties are discussed." @default.
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- W2008553789 date "2002-10-01" @default.
- W2008553789 modified "2023-10-16" @default.
- W2008553789 title "Preparation of divalent rare earth ions in air by aliovalent substitution and spectroscopic properties of Ln2+" @default.
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- W2008553789 doi "https://doi.org/10.1016/s0925-8388(02)00351-1" @default.
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