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- W2008556559 abstract "The intensity of Raman modes of four different silicate garnets in the energy range 1.9–2.7 eV was investigated. In the case of almandine (Fe3Al2Si3O12) and pyrope (Mg3Al2Si3O12) no change in intensities was observed in this energy region and in uvarovite (Ca3Cr2Si3O12) a weak resonance maximum was observed between 2.2 and 2.4 eV. Andradite (Ca3Fe2Si3O12), however, showed a strong resonance in the blue energy range with two maxima at 2.4 and 2.6 eV. The strongly enhanced resonances in andradite, compared with the other three garnets, is thought to be caused by electronic transitions in the eg states of Fe3+ in the octahedral site. The individual resonance behavior of two components (Eg,1 and Eg,2) of the same twofold degenerate Eg mode related to the SiO4 tetrahedron can be distinguished by the interaction of the respective Raman and Fe3+ electronic eg-state tensors. © 1997 John Wiley & Sons, Ltd." @default.
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- W2008556559 date "1997-09-01" @default.
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- W2008556559 title "Raman scattering in silicate garnets: an investigation of their resonance intensities" @default.
- W2008556559 doi "https://doi.org/10.1002/(sici)1097-4555(199709)28:9<659::aid-jrs156>3.0.co;2-7" @default.
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