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- W2008557978 abstract "Abstract H 2 and D 2 are scattered from clean Pd(111) and a saturated chemisorption layer in a highly specular distribution. Evidence for an ordering of the adiayer with increasing coverage is seen. The hydrogen-deuterium exchange occurs via a Langmuir-Hinshelwood mechanism, and the temperature dependence of the rate of HD production can be understood without assuming an activation energy for equilibration. Lock-in and wave-form analyses of scattered H 2 + D 2 mixed beams show that equilibrium between adsorbed hydrogen and deuterium and that dissolved just below the surface is reached rapidly at temperatures above 300 K." @default.
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- W2008557978 date "1979-12-01" @default.
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- W2008557978 title "A molecular-beam investigation of the scattering, adsorption and absorption of H2 and D2 from/on/in Pd(111)" @default.
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- W2008557978 doi "https://doi.org/10.1016/0039-6028(79)90017-7" @default.
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