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- W2008596806 abstract "A method of preparing RuTp(η4-diene)Cl complexes (diene = 1,3-butadiene, 2-methyl-1,3-butadiene, 2,4-hexadiene) is described, proceeding from RuTp(COD)Cl (COD = cycloocta-1,5-diene) through the intermediacy of Ru(III). The acyclic diene ligands are attached to the metal center in an s-trans manner, both in the solid state and in solution. So strong is the preference for trans-diene coordination that when a cyclic diene (1,3-cyclohexadiene) is used, elimination of HCl occurs yielding the η5-cyclohexadienyl complex RuTp(η5-C6H7)." @default.
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- W2008596806 date "1997-06-01" @default.
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- W2008596806 title "Ruthenium Tripyrazolylborate Complexes. 8. <i>trans</i>-Diene Coordination in Ruthenium Tripyrazolylborate Complexes" @default.
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